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Home Nanoclays
Nanoclays

Introduction to Nanoclays

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Why settle for this? 
When you can have this?
Single Screw Alone Single Screw + Tek-MixTM

Nanoclay Masterbatches: 40% Nanomer I.44P + 60%  HDPE produced on single screw extrusion lines without any MAH compatibilizer, shown on compression molded sheets.  The single screw extruder shows poor dispersion as expected.   The Tek-Mix™ product exceeds dispersion from the twin-screw extruder.

What is Special About Nanoclays?

Fillers of all types are not new to plastic compounding.   The introduction of nano-sized particles, though, has generated considerable interest in the plastics industry because of some very attractive performance benefits derived from properly dispersed composite materials.    Early claims involving dramatically improved barrier properties, improved flame retardancy, improved stiffnes, as well as improved tensile and flexural properties, have often been unfulfilled because the existing mixing and blending technologies were not sufficient to achieve the necessary dispersions of particles without adding so much pressure, heat, and energy to the operation that the particles agglomerated before the process was completed, and the host resin suffered some molecular degradation. 

The Stratek Benefit:

Stratek's Tek-MixTM technology is an excellent complement to conventional mixing and blending methods because its low temperature, low pressure, low shear, and natural ability to achieve particle size reduction and dispersion, offers a mixing enhancement to any single or twin-screw extruder to improve nanoclay dispersion and exfoliation.  With the aid of Tek-MixTM technology, single screw extruders can now perform similarly to twin-screw extruders.  The resulting benefits from using Tek-MixTM technology  to enhance single or twin-screw mixing are:

  1. Particle Size Reduction   
  2. Elimination of fine mesh screens
  3. Reduction in extruder backpressure.
  4. In many cases, improved physical properties, especially tensile and flexural strength and modulus, both through better dispersion and due to reduction in degradation of the host polymer.
  5. In certain cases, substitution of untreated neat nanoclay in place of expensive organo-coated clays.
  6. Substitution of higher strength and higher viscosity carrier resins to increase physcial properties.  Using these alternate higher molecular weight resins will provide improved physical properties including the following:

- Environmental stress resistance
- Impact strength
- Abrasion resistance
- Melt strength
- Melt viscosity 

For discussions of processing tests the resulting technical data, please see the Stratek Case Histories.
 
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Nanoclay Case History 1:  Nylon (PA) + Nanoclay with Organocoating
The following Tensile Modulus and Flexural Modulus data was generated by Stratek during processing trials involving a standard Nylon (PA) 6 matrix material into which Stratek mixed Nanocor's I30P, a
Nanocor Montorillonite clay (MMT-ODA).   This nanoclay material is an octadecyl amine modified material having a modified surface which acts as a compatibilizing agent for PA 6 material.   The trials were conducted at varying nanoclay concentrations, as indicated by the labels for each value in the bar charts.    Since these trials were established to provide comparitive improvement data relative to the virgin material rather than comparing the effectiveness of a single-screw extruder to a twin-screw extruder,  the 100% value was ascribed to the virgin PA 6 material, which was tested both "as received"  from its manufacturer and then later, following Tek-MixTM  mixing.   The processing trials included the use of both single- and twin-screw extruders, however the Tek-MixTM trials were performed with the Tek-MixTM mixer directly attached in-line with a single-screw extruder.  The objective was improved Tensile Modulus.

 


Dispersion Test Results:  Full, Even Dispersion Achieved
A standard test for determining the efficiency of the dispersion of nanoclay particles is the non-destructive X-Ray Diffraction (XRD) test.   The XRD test measures the degree of dispersion by measuring the scattered light pattern formed when a scan of X-Ray beams encounters the composite.   These measurements are used to estimate the distance between individual platelets after compounding.  The result is that the greater and more even the dispersion, the fewer "reflections" (manefested as "peaks" on the graph below), indicating the more complete and even the dispersion.  For customers seeking improved physical properties such as improved barrier capability or increased tensile or flexural qualities, a successful dispersion is essential.  
   
The following table shows XRD data captured during this processing trials involving PA 6 and nanoclay.    The table shows the distance spacings for the particles before and after Tek-MixTM processing. The increases in the "d-space" confirm that the PA 6 matrix material has successfully interacted with the particles, thereby forming a true composite material. 


Sample
2θ/
d-space
2θ/
d-space
2θ/
d-space
2θ/
d-space
2θ/
d-space
2θ/
d-space
2θ/
d-space
Nanomer
130P NanoClay
3.5 (2θ)
24.73 Å
8.1 (2θ)
10.86 Å
19.7 (2θ)
4.48 Å
26.6 (2θ)
3.35 Å
28.7 (2θ)
3.10 Å
35.1 (2θ)
2.54 Å
61.8 (2θ)
1.49 Å
 
Nylon 6
9.3 (2θ)
9.41 Å
 
12.3 (2θ)
7.14 Å
20.4 (2θ)
4.34 Å
23.8 (2θ)
3.73 Å
 
28.5 (2θ)
3.12 Å
Nanomer
130P NanoClay
+
 Nylon 6
9.3 (2θ)
9.41 Å
10.6 (2θ)
8.29 Å
12.3 (2θ)
7.14 Å
20.4 (2θ)
4.34 Å
23.8 (2θ)
3.73 Å
26.6 (2θ)
3.35 Å
28.5 (2θ)
3.12 Å

The graph below shows the XRD results for (a) the virgin, unfilled Nylon material (labeled PA 6 and coded as the red curve), (b) the curve formed by the clay material itself (black), and (c) the curve developed by the Stratek Tek-MixTM Nylon and clay composite (blue).  


What is seen is that "reflection" in the black line (clay) occurs in the viscinity of 4 Å (Angstoms), but that it does not appear in the composite material.   These results suggest that either the clay material was completely absent from the sample tested by the XRD, or that the clay material was evenly dispersed.   Further tests (Thermogravimetric Analysis, TGA) confirmed the presence of the nanoclay material in the tested specimen, therefore the conclusion is that the nanoparticles are dispersed as the XRD test suggests.  

Each XRD powder pattern was collected with a panalytical X, Pert Pro MD System using a copper X-Ray source operating at 45KV / 40mA.  An in-line nickel filter was positioned on the diffracted beam side of the insrument to reduce CuKß signal contribution in the collected powder pattern.

Morphology:  Individual Particles Not Visible 
Below are two SEM's photos of the treated material.  No nanoclay is visible, however EDX tests did confirm the presence of the clay.


Photos courtesy of PolyOne Corporation

Summary:  Both the Tensile Modulus and Flexural Modulus test values of this organo-coated clay and Polyamide composite were increased when a Stratek Tek-MixTM mixer was added in-line, directly to the output of the single screw extruder.  The Flexural Moduls figures for the single screw +Tek-MixTM mixer were approximately equal (166% and 173% over virgin resin) to the results achieved by the twin-screw extruder alone (165%), and the Tensile Modulus figures for the same processing configurations were actually higher (171% and 201%) than the twin-screw extruder (136%) achieved alone. 



 


Newsflash

From the Stratek Reading Room...

"The Materials Analyst, Part 98:  A Tour of the World of Nylon-Part 1"
An Article by Michael Sepe, published in Injection Molding Magazine - July 2008

Stratek has done considerable experimentation and material processing involving Polyamides (Nylon).  Therefore this article caught our eye when we found it in the July Issue of Injection Molding Magazine.   We think it addresses both the basics and some more advanced information concerning the differences in the chemistry and structure of these two important materials.

Read more...